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    三塘湖盆地淖毛湖凹陷八道湾组煤的有机地球化学特征

    Organic geochemical characteristics of coal in the badaowan formation of the Naomaohu Sag, Santanghu basin

    • 摘要: 为阐明三塘湖盆地淖毛湖凹陷八道湾组1号煤层的富氢有机质来源、沉积环境及热演化特征,本研究采用煤岩学显微组分鉴定、镜质体反射率测定、饱和烃与芳香烃的色谱−质谱(GC-MS)分析等有机地球化学方法。显微煤岩组分和生物标志化合物分析表明,氢指数高的蕨类植物、富含树脂的松柏类植物和富饱和烃的低等水生生物是煤中富氢有机质的主要来源。研究发现,强覆水且有一定水体流动的还原环境有利于高等植物富氢组分(孢子、角质体等)的保存与富集,同时还为成岩早期壳质组释放的可溶有机质向镜质体渗透富集提供了条件。镜质体反射率(0.40%~0.48%)表明,有机质处于未熟–低熟阶段,部分富氢有机质已具有生油能力,是富油煤形成的有利阶段。

       

      Abstract: In order to clarify the source, sedimentary environment and thermal evolution characteristics of hydrogen-rich organic matter in No.1 coal of Badaowan formation in Naomaohu Sag, Santanghu basin, this study used organic geochemical methods such as coal petrographic maceral identification, vitrinite reflectance determination, and gas chromatography-mass spectrometry (GC-MS) analysis of saturated hydrocarbons and aromatic hydrocarbons. Maceral composition and biomarker compounds analyses indicate that ferns with high hydrogen indices, conifers rich in resins, and lower aquatic organisms abundant in saturated hydrocarbons are the primary sources of hydrogen-rich organic matter in the coal. The results show that the reducing environment with strong overlying water and certain water flow is conducive to the preservation and enrichment of hydrogen-rich components (spores, cuticles, etc.) in higher plants, and also provides conditions for the infiltration and enrichment of soluble organic matter released by early diagenetic exinite to vitrinite. The vitrinite reflectance (0.40% ~ 0.48%) indicates that the organic matter is in the immature-low mature stage, and some hydrogen-rich organic matter has the ability to generate oil, which is a favorable stage for the formation of oil-rich coal.

       

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